Hi
looking at it with MINDSUPERB's comment in mind but from the other direction.
If you pick from a RGB range like your colour picker shows AND your document is in CMYK mode, Illustrator will adjust your colours to CMYK, which usually looks darker and/or duller.
That is normal. You can check the behavior by looking at the colour sliders. If they show CMYK values at xx.xx in fractions rather than full intergers than you had RGB=>CMYK converted.
if you design for print you need to adjust theseto corresponding CMYK values as the conversion usually over-inks, specifying too much ink to be applied, which your printer will reject.
If you only design for on screen use, make sure your document settings are RGB only.
hth
capt.
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by: MINDSUPERBPosted on 2008-09-24 at 00:13:43ID: 22557462
luefher,
You may check that your document colour mode is on CMYK (File>Document colour mode>CMYK). By concept, even if you change your colour tool tab from RGB to CMYK, Illustrator will still convert it back to RGB unless your document mode is on CMYK.
Let me know if it doesnt fix the issue.
Ed