Error to print crystal report from IIS

//web application
 
private void Imprimir()
    {
        logger.Debug(string.Format("Imprimir"));
 
        string nombreFichero = Server.MapPath(@"~\Serializacion") + "\\Informe_" + DateTime.Now.ToString("yyyyMMdd") + "_" +
            DateTime.Now.ToString("HHmmss") + ".rpt";
 
        ReportDocument reportDocument = (ReportDocument)Session["report"];
        if (reportDocument != null)
        {
            reportDocument.SaveAs(nombreFichero, true);
        }
 
        string rutaEjecutable = Server.MapPath(@"~\bin\Impresion.exe");
 
        ProcessStartInfo startInfo = new ProcessStartInfo(rutaEjecutable);
 
        startInfo.Arguments = nombreFichero;
 
        Process process = Process.Start(startInfo);
 
        while (!process.HasExited)
        {
        }
 
        process.Close();
        process.Dispose();
    }     
 
//windows application
private void Form1_Load(object sender, EventArgs e)
        {
            try
            {
                throw new Exception("hola");
                ReportDocument reportDocument = new ReportDocument();
                reportDocument.Load(@"C:\Inetpub\wwwroot\WebSetupPLS\Serializacion\Informe_20080121_123421.rpt");
 
                if (reportDocument != null)
                {
                    PrintDialog printDialog = new PrintDialog();
                    if (printDialog.ShowDialog() == DialogResult.OK)
                    {
                        reportDocument.PrintOptions.PrinterName = printDialog.PrinterSettings.PrinterName;
                        reportDocument.PrintToPrinter(printDialog.PrinterSettings.Copies, printDialog.PrinterSettings.Collate,
                            printDialog.PrinterSettings.FromPage, printDialog.PrinterSettings.ToPage);
 
                    }
 
                    reportDocument.Close();
                    reportDocument.Dispose();
                }
            }
            catch (Exception ex)
            {
            }
 
            Application.Exit();
        }