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Start with use View | Toolbar | Customize. Right-click on the button you want to customize, and change its Name to include an ampersand ( &amp;&nbsp;) in front of the letter that you want to use as a hotkey with the Alt key. 
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Start with use View | Toolbar | Customize. Right-click on the button you want to customize, and change its Name to include an ampersand ( & ) in front of the letter that you want to use as a hotkey with the Alt key.

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Is there any way to do it programmatically using VB, VBA or VBScript?
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Is there any way to do it programmatically using VB, VBA or VBScript?

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In Outlook 2000, yes, you have the complete Office CommandBars object to work with. The CommandBarButton.Caption property is the equivalent of the Name in the UI.
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In Outlook 2000, yes, you have the complete Office CommandBars object to work with. The CommandBarButton.Caption property is the equivalent of the Name in the UI.

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Can show a sample code for me to follow?
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How am i able to link hot keys to control buttons created in both Menu file and toolbars?
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How am i able to link hot keys to control buttons created in both Menu file and toolbars?

How to add hot keys to an added control button

Microsoft Outlook is a personal information manager from Microsoft, available as a part of the Microsoft Office suite. Although often used mainly as an email application, it also includes a calendar, task manager, contact manager, note-taker, journal, and web browser.