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[Autorun]
Open=MyFolder\myExe.exe
I'm not quite sure if the autorun will run for a none exe file (in this case .pps file)
But here is a workaround, as for the above statement:
Open=MyFolder\myExe.exe
create an exe at MyFolder name it as myExe.exe
That by generating the myExe.exe file, we open the pps by using Shell function, example using VB:
Create a form, in the Form_Load Event:
Shell [my pps file's path]
Hope this make help