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I have all windows xp machine in one domain. Creating the MSI package is pain 
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I have all windows xp machine in one domain. Creating the MSI package is pain

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Without creating your own MSI, then it's totally dependent on the uninstall of the particular program. You need to find the uninstall string for the program you want to uninstall, then send that command using psexec, or as a batch file in a logon script etc.<br />
For most programs you can find the uninstall string by looking in HKEY_LOCAL_MACHINE\SOFTWAR<wbr />E\Microsof<wbr />t\Windows\<wbr />CurrentVer<wbr />sion\Unins<wbr />tall<br />
Find the program in question there and get the value for UninstallString.
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Without creating your own MSI, then it's totally dependent on the uninstall of the particular program. You need to find the uninstall string for the program you want to uninstall, then send that command using psexec, or as a batch file in a logon script etc.
For most programs you can find the uninstall string by looking in HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows\CurrentVersion\Uninstall
Find the program in question there and get the value for UninstallString.

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Do i need a clean comuputer for MSI package. Do any one have better document for creating MSI. 
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Do i need a clean comuputer for MSI package. Do any one have better document for creating MSI.

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I have many xp workstations in my work enviornment. I would like to uninstall a software from all machine. Is there any way i can do it from my workstation? <br />
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1. I would not like to remote desktop since it will throw the user session. <br />
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please advice. 
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I have many xp workstations in my work enviornment. I would like to uninstall a software from all machine. Is there any way i can do it from my workstation? 

1. I would not like to remote desktop since it will throw the user session. 

please advice. 

Uninstalling software remotely.

Installation is the act of making a computer program program ready for execution. Because the process varies programs often come with a specialized program responsible for doing whatever is needed for their installation. Installation may be part of a larger software deployment process. Cross platform installer builders that produce installers for Windows, Mac OS X and Linux include InstallAnywhere, InstallBuilder and Install4J. Installers for Microsoft Windows include Windows Installer, InstallShield, and Wise Installation Studio; free installer-authoring tools include NSIS, IzPack, Clickteam, InnoSetup, InstallSimple and WiX. Mac OS X includes Installer, and also includes a separate software updating application.

Installation

Microsoft Windows XP is the sixth release of the NT series of operating systems, and was the first to be marketed in a variety of editions: XP Home and XP Professional, designed for business and power users. The advanced features in XP Professional are generally disabled in Home Edition, but are there and can be activated. There were two 64-bit editions, an embedded edition and a tablet edition.