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PHP is a widely-used server-side scripting language especially suited for web development, powering tens of millions of sites from Facebook to personal WordPress blogs. PHP is often paired with the MySQL relational database, but includes support for most other mainstream databases. By utilizing different Server APIs, PHP can work on many different web servers as a server-side scripting language.
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I'm certainly no expert on email, but I don't think they get marked as spam because of when they were sent, and certainly not in comparison to the next message sent. Outside of the originating server, one message has absolutely no relation to the next. I've sent more than 6000 emails in a single batch and never had an issue with them being marked as spam. From my *very* basic knowledge of spam filters, they look at other characteristics like content, address resolution, etc. Perhaps there is something in your content triggering the spam filter?