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Is there a parameter that you can set using VBA to send an email with an alternative mailbox's email address if you have access to that Mailbox? 
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Is there a parameter that you can set using VBA to send an email with an alternative mailbox's email address if you have access to that Mailbox? 

Send mail from alternative mailbox within Outlook using VBA

Visual Basic is Microsoft’s event-driven programming language and integrated development environment (IDE) for its Component Object Model (COM) programming model. It is relatively easy to learn and use because of its graphical development features and BASIC heritage. It has been replaced with VB.NET, and is very similar to VBA (Visual Basic for Applications), the programming language for the Microsoft Office product line.

Visual Basic Classic

Microsoft Outlook is a personal information manager from Microsoft, available as a part of the Microsoft Office suite. Although often used mainly as an email application, it also includes a calendar, task manager, contact manager, note-taker, journal, and web browser.

Outlook

Within Internet message handling services (MHS), a message transfer agent or mail transfer agent (MTA) or mail relay is software that transfers electronic mail messages from one computer to another using a client–server application architecture. A MTA implements both the client (sending) and server (receiving) portions of the Simple Mail Transfer Protocol (SMTP). The terms mail server, mail exchanger, and MX host may also refer to a computer performing the MTA function. The Domain Name System (DNS) associates a mail server to a domain with mail exchanger (MX) resource records containing the domain name of a host providing MTA services.