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How to change the default sending account to Exchange for a user on Exchange with a Pop3 account

I added a pop3 email account in Outlook for a user already on our Exchange 2003 system so that he can pick up his mail from his old address where he was before. Is is possible to setup Outlook to use by default Exchange when replying to these pop3 emails instead of the smtp server entered in the Pop3 account configuration ? Right now he has to select "Microsoft Exchange Server" instead of the pop3 account name in the Account drop-down list button when in the Reply window. Besides that, Exchange is his default account.
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Dave Stringfellow
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