sendmail mailq ~ Recipient address rejected: Service is unavailable

Gday Experts

just set up my website was doing some test emails from a form I setup using pear mail, everything was working then I stopped receiving the mails and cant figure out why, now I know the script works because if i send to my personal email, all is fine, but when sending to work email, they are not recieved, the email goes to the mailq when I try to flush it i get this... Any ideas guys, Sincerely -- Zemond

Running /var/spool/mqueue/m75HD72O022823 (sequence 1 of 1)
<james.butler@hcagroup.com.au>... Connecting to filter1.hcagro-1.mailguard.com.au. via esmtp...
220 natrium.mailguard.com.au ESMTP Postfix
>>> EHLO hca-online.com
250-natrium.mailguard.com.au
250-SIZE 52428800
250-VRFY
250-ETRN
250-AUTH DIGEST-MD5 PLAIN LOGIN
250-AUTH=DIGEST-MD5 PLAIN LOGIN
250-ENHANCEDSTATUSCODES
250 8BITMIME
>>> MAIL From:<apache@hca-online.com> SIZE=995
250 2.1.0 Ok
>>> RCPT To:<james.butler@hcagroup.com.au>
459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
<james.butler@hcagroup.com.au>... Deferred: 459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
>>> RSET
250 2.0.0 Ok
Connecting to filter2.hcagro-1.mailguard.com.au. via esmtp...
220 helium.mailguard.com.au ESMTP Postfix
>>> EHLO hca-online.com
250-helium.mailguard.com.au
250-SIZE 52428800
250-VRFY
250-ETRN
250-AUTH PLAIN LOGIN DIGEST-MD5
250-AUTH=PLAIN LOGIN DIGEST-MD5
250-ENHANCEDSTATUSCODES
250 8BITMIME
>>> MAIL From:<apache@hca-online.com> SIZE=995
250 2.1.0 Ok
>>> RCPT To:<james.butler@hcagroup.com.au>
459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
<james.butler@hcagroup.com.au>... Deferred: 459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
>>> RSET
250 2.0.0 Ok
Connecting to filter3.hcagro-1.mailguard.com.au. via esmtp...
Closing connection to filter1.hcagro-1.mailguard.com.au.
>>> QUIT
221 2.0.0 Bye
220 tungsten.mailguard.com.au ESMTP Postfix
>>> EHLO hca-online.com
250-tungsten.mailguard.com.au
250-SIZE 52428800
250-VRFY
250-ETRN
250-AUTH PLAIN LOGIN DIGEST-MD5
250-AUTH=PLAIN LOGIN DIGEST-MD5
250-ENHANCEDSTATUSCODES
250 8BITMIME
>>> MAIL From:<apache@hca-online.com> SIZE=995
250 2.1.0 Ok
>>> RCPT To:<james.butler@hcagroup.com.au>
459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
<james.butler@hcagroup.com.au>... Deferred: 459 4.7.1 <james.butler@hcagroup.com.au>: Recipient address rejected: Service is unavailable
>>> RSET
250 2.0.0 Ok
Closing connection to filter2.hcagro-1.mailguard.com.au.
>>> QUIT
221 2.0.0 Bye
Closing connection to filter3.hcagro-1.mailguard.com.au.
>>> QUIT
221 2.0.0 Bye