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Microsoft Windows XP is the sixth release of the NT series of operating systems, and was the first to be marketed in a variety of editions: XP Home and XP Professional, designed for business and power users. The advanced features in XP Professional are generally disabled in Home Edition, but are there and can be activated. There were two 64-bit editions, an embedded edition and a tablet edition.
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Extract the .EXE to the C Drive.
Open up Command Prompt, and type this in:
C:\wolcmd MACADDRESS 255.255.255.255 255.255.255.255
To find a computer's MACADDRESS, ping the machine from your computer by its IP ADDRESS.
The type in: arp -a to get the list of your ARP table, in there you should find the MAC address associated with that machine.
For more help with the WOLCMD commands, see this http://www.depicus.com/wake-on-lan/wake-on-lan-cmd.aspx