Send As permission for admin account

The blackberry service account should have Send As permissions on users objects. Did you checked that

Everytime I check Send As permission under my account for Besadmin it dissappears.

Is your account part of 'Restricted Accounts'

It will disappear every hour as a security precaution.

If you modify the security properties on the AD object "AdminSDHolder" it will not disappear.  The AdminSDHolder folder is what administrators get reset to every hour.  You need to enable advanced view in ADUC.

Here's a link that BB sent me when I had the same exact issue:

http://na.blackberry.com/eng/support/software/sendas.jsp

Gives lots about SendAs.

Here is the link specific to your issue: http://www.blackberry.com/btsc/search.do?cmd=displayKC&docType=kc&externalId=KB12309

Also, your BESAdmin should be a regular user, not an admin.

BesAdmin is a regular user in my AD.

Does this happens only with your account or with all the accounts.

It looks to me like your account is Admin account and it is part of 'Restricted accounts' where it will revert any changes made on your account, I would suggest you to use different account for email and not use your admin account for email