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Creating dummy pop account in Outlook 2007 for Exchange 2007.

I have an Exchange 2007 server that is authoritative for two domains.  One user has an email address for both domains (user@domain1.com and user@domain2.com are both aliased to his user).  His default address is user@domain1.com which is set up using an exchange account set up in Outlook 2007. This user would like to be able to send out of either email address by choice.  I created a dummy pop3 account in his Outlook 2007, but I've run into an issue.

If I set outgoing authorization in the dummy POP account to nothing, he can send a test email to himself through the dummy account just fine.  However, if I try to send an email to anyone else, I get an NDR stating "Unable to relay."  If I try to put in his user account details into the dummy POP account's outgoing authorization, I just get a popup asking for a username and password over and over again, though I am certain the username and password is correct.  I've tried multiple entries for the username including domain\username, username@domain.com, and username.  Does anyone have any ideas on why this is happening?
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Bikkelbink

Hi DataDudes,

Have you enabled TLS encryption in your client?
Which port are you using for your SMTP 25 or 587?

Regards,
BB
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ASKER

I've tried with and without TLS and SSL on the client.  I am using port 25
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Bikkelbink

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I do not get a popup stating the certificate is not trusted or valid.  I've tried using port 587 for outbound smtp, but I still get the popup asking me for my username and password.
Using port 587 and adding the domain/user with no authentication seems to have done the trick.  Thanks for the help!