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http://www.experts-exchange.com/OS/Microsoft_Operating_Systems/Server/Windows_Server_2008/A_3296-The-Absolute-Beginner's-Guide-to-Powershell.html
And when you're done with that, and you want to know how it can benefit your life as a Server Administrator, you can check out this article:
http://www.experts-exchange.com/Programming/Languages/Scripting/Powershell/A_4327-PowerShell-Where-do-I-start.html
It goes into a little more depth of how you can unlock accounts very easily, reset passwords, and even create accounts. Powershell is the future and it's the "Console" for Exchange 2007, Exchange 2010, and Sharepoint 2010. It's definitely here to stay and made to improve upon VBS with a .Net flair.
HTH,
Dale Harris