I have 2 users getting all emails to their own domain bounced. For example User1@abcd.com in Phoenix sending to User2@abcd.com in Chicago will bounce. But User1 can send to a different domain no problem.
Within the SAME local network the emails go just fine.
I believe there is a setting in Exchange 2010 needed for this but I can't recall.
If you are sharing the domain name across two servers, you need to configure the servers to be internal relay domains:
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