//1st way..
Session.Add("Key","Value");
//2nd way..
Session["Key"] = "Value";
Here Key must be a string qualifier for the Session variable i.e name of the variable. And Value part is actually of object type which can store any of the two value or reference type. In the above case I have used a String type with value as "Value".
Small information, one page to another, use querystring. Othewise use session variables.
Also, session variables will be available from any page until it is killed or expired.
QueryStrings are used to pass values from just one page to another.