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Oracle is an object-relational database management system. It supports a large number of languages and application development frameworks. Its primary languages are SQL, PL/SQL and Java, but it also includes support for C and C++. Oracle also has its own enterprise modules and application server software.
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The advantage is it lets you organize a table in the order most commonly accessed, and lets you combine storage for a heap table + primary key.
A typical heap table in Oracle has no ordering. Then you create a primary key index which is stored in a 2nd segment. So you have to segments of data now. Also you have redundant storage of the indexed columns. So when querying by the primary key, Oracle has to first access the index, then the table in most cases.
An IOT gets rid of the redundancy, and also orders the rows in the actual table, because it is an index, with the additional difference that the IOT also has the full data for each row stored in it, not just the keys.