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The Windows operating systems have distinct methodologies for designing and implementing networks, and have specific systems to accomplish various networking processes, such as Exchange for email, Sharepoint for shared files and programs, and IIS for delivery of web pages. Microsoft also produces server technologies for networked database use, security and virtualization.
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Appart from that kind of solution, you should be able to team NICS from the client of your NAS...but that won't allow to get a single file faster, it will allow to have 2 Gbe streams from your client.