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We have few users who need to access Office 2010 in Citrix Full desktop which also has Office 2003. Is this possible?
Yes, this is possible with App Streaming. If it were me, Plan A would be to put up a couple of extra servers (at least 2 for redundancy) just to service those users, and Plan B would be to stream Office 2010 to those same servers.
Is application streaming feature available in XenApp 4.5 Enterprise edition. This is what we have.
Yes, Application streaming feature available in XenApp 4.5 Enterprise edition.