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Here's a few free online tutorials to start with ....<br />
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<a href="http://www.w3schools.com/aspnet/default.asp" rel="ugc">http://www.w3schools.com/aspnet/default.asp</a><br />
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<a href="http://asp.net-tutorials.com/" rel="ugc">http://asp.net-tutorials.com/</a><br />
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<a href="http://www.java2s.com/Tutorial/ASP.NET/CatalogASP.NET.htm" rel="ugc">http://www.java2s.com/Tutorial/ASP.NET/CatalogASP.NET.htm</a>
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Here's a few free online tutorials to start with ....

http://www.w3schools.com/aspnet/default.asp [http://www.w3schools.com/aspnet/default.asp]

http://asp.net-tutorials.com/ [http://asp.net-tutorials.com/]

http://www.java2s.com/Tutorial/ASP.NET/CatalogASP.NET.htm [http://www.java2s.com/Tutorial/ASP.NET/CatalogASP.NET.htm]

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I am preparing asp.net 4.0 MCTS. 
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Do you buy many books? Or just follow MSDN?<br />
I hate to buy books because they are expensive and maybe not helpful. But if without a book, memory all concepts and methods/properties is not an easy thing.<br />
Web form, MVC, Jquery, AJAX, Silverlight....too manyyyyy!
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Do you buy many books? Or just follow MSDN?
I hate to buy books because they are expensive and maybe not helpful. But if without a book, memory all concepts and methods/properties is not an easy thing.
Web form, MVC, Jquery, AJAX, Silverlight....too manyyyyy!

How do you learn asp.net?

The successor to Active Server Pages, ASP.NET websites utilize the .NET framework to produce dynamic, data and content-driven web applications and services. ASP.NET code can be written using any .NET supported language. As of 2009, ASP.NET can also apply the Model-View-Controller (MVC) pattern to web applications