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Just add a new accepted domain in the exchange console then edit your address policy to auto update your users with the a new email address on the new domain.
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Just add a new accepted domain in the exchange console then edit your address policy to auto update your users with the a new email address on the new domain.

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Sorry for being thick - what I was asking is, where do I find the things you've listed here?
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Sorry for being thick - what I was asking is, where do I find the things you've listed here?

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BINGO - that was it - thanks!!
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Hi - our company wishes to start using a new domain in order to receive emails. I am confident in setting up the DNS MX records in order to deliver the email messages to our Exchange 2010 server - but need some guidance on the steps I need to follow on the server. I still wish to receive emails using our old email domain. Also, I'd like to use the new domain in the default 'from' address for all emails that people send. Thanks Ed. 
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Hi - our company wishes to start using a new domain in order to receive emails. I am confident in setting up the DNS MX records in order to deliver the email messages to our Exchange 2010 server - but need some guidance on the steps I need to follow on the server. I still wish to receive emails using our old email domain. Also, I'd like to use the new domain in the default 'from' address for all emails that people send. Thanks Ed. 

Adding new email domain to Exchange 2010

Exchange is the server side of a collaborative application product that is part of the Microsoft Server infrastructure. Exchange's major features include email, calendaring, contacts and tasks, support for mobile and web-based access to information, and support for data storage.