4.0 and wcf

Hi experts, I am about to start the new .net project.
I will use 4.0 and WCF Technologies.
I want to keep core functionality of the project inside WCF Service hosted on windows server 2008 service application  and
use 4.0 Web Application which talks with this wcf service for user interface,
Can you provide me some suggestion, know how, profession, clear documantation and sample code for this.
Who is Participating?
For WCF, I found webcasts from Aaron Skonnard very useful. If you are completely new to WCF, you should watch the webcasts at this link:

The videos are listed under "Introductory Videos".
esbasitAuthor Commented:
I was expecting more dedicated samples and information about the question topic.Thanks...
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