troubleshooting Question

Exchange 2010 - Outlook 2010 - Using multiple exchange email accounts in one profile.

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Currently utilizing 2 domains in Exchange and need to have the ability for users to choose between and in Outlook 2010 while composing a new email. Both domains are resident in the Hub Transport. But will only auto discover the primary 'reply' domain default in EMC. Attempting to manually setup an additional exchange mailbox for a single profile results in an error stating it's a duplicate mailbox.
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