Sending mail from non predeterminated email address

I have an Exchange 2010, I have an user with its corresponding mailbox. This user  has different mail addresses, and one of them is set in response address. I can receive the mails sent to any of the address, every time I try to send a mail the response address is added in the FOR, that is correct.
I have tried to sent mails using one of the no predeterminated mail address in the FROM field (directly typing) but when I open the recived mail I can only see the Response address.

My question is, can I use any of the  other mail account in the FROM field?
Who is Participating?
Simon Butler (Sembee)Connect With a Mentor ConsultantCommented:
As far as Exchange is concerned, all users only have one email address - the primary. All others are aliases for inbound email ONLY. You cannot just enter another address in the from field and expect it to work.

Therefore you have a number of choices.
1. Setup additional mailboxes.
2. Use a third party tool ChooseFrom.

Additional mailboxes do not require additional CALs. The user would require permissions to Send As the additional mailbox.

R--RConnect With a Mentor Commented:
You can send mail by selecting email address in from field provided th eemail address should belong to that user.

check this from and
limmontreefreeAuthor Commented:
thanks It's not easy and not free. but's there is.
Simon Butler (Sembee)ConsultantCommented:
The native additional mailbox solution is free - it doesn't use any additional CALs.

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