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Exchange is the server side of a collaborative application product that is part of the Microsoft Server infrastructure. Exchange's major features include email, calendaring, contacts and tasks, support for mobile and web-based access to information, and support for data storage.
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1. Make a new group with the 1st half of the address list.
2. Test the new group. Did it fail?
3. If it failed, the problem is in this group of addresses. Cut this list in half again, go to step #2 and test.
4. If it did not fail, the problem is in the 2nd half of the list. Go to step #2 above and test.
You'll either narrow the problem down to a single email address, or you have a very odd case. Either way, you'll narrow down the problem. Of course, beware of having two or more bad addresses causing the problem.