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The Microsoft Legacy Operating System topic includes legacy versions of Microsoft operating systems prior to Windows 2000: All versions of MS-DOS and other versions developed for specific manufacturers and Windows 3/3.1, Windows 95 and Windows 98, plus any other Windows-related versions, and Windows Mobile.
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RDP printing is based on default printer on local pc. Second thing is yes you can open print server on server and change security on PDF printer to disalow user to use it. So he will be having 2 printers one localy one remotly but remote one he cant use becouse of restrictions.