DECLARE @workDays int, @calDays int,@NextRunDate datetime
SET @workDays = 6
SELECT @calDays = @workDays / 5 * 7 + @workDays % 5
WHILE DatePart(dw, DateAdd(dd, @calDays, '01/01/2014')) IN (7, 1)
SET @calDays = @calDays + 1
SELECT @NextRunDate = DateAdd(dd, @calDays-1, '01/01/2014')
Update schedules set NextRunDate = @NextRunDate
-- Add your WHERE condition if needed.
Reason I ask is because SQL Server does not have a 'business day' function, and everyplace is different. National holidays, state holidays, Green Bay Packers football games, Dave's birthday, special events, etc.
I have an article out there on How to build a SQL Calendar Table, that will enable you to have a table of days, and specifically define what's a business day and what's not, so that you can pull off a 'give me the 6th business day' and be guaranteed of success.
Good luck.