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Hmm.. I would go in a different direction.. <br />
Im not too sure if this will work based on your version of outlook but you may want to try<br />
<br />
Have the application by default log into the kids one.. <br />
Then when you want to run the program right click + shift on the outlook icon and select run as<br />
type in your password and this should bring up a different set of options for you.<br />
<br />
That way when you want to run outlook you need to type in your password.. otherwise the kids will load by default.
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Hmm.. I would go in a different direction..
Im not too sure if this will work based on your version of outlook but you may want to try

Have the application by default log into the kids one..
Then when you want to run the program right click + shift on the outlook icon and select run as
type in your password and this should bring up a different set of options for you.

That way when you want to run outlook you need to type in your password.. otherwise the kids will load by default.

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Profile selection (Mail properties) works from Outlook 2003 through to Outlook 2013 so it should work here.
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Profile selection (Mail properties) works from Outlook 2003 through to Outlook 2013 so it should work here.

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Thank you ! Good info, both of you.
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@bleggee &nbsp;- You are very welcome and I was happy to help.
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@bleggee  - You are very welcome and I was happy to help.

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I have mutliple EMAIL Accounts in my Outlook right now, no problem<br />
HOWEVER<br />
What I want to do is use Outlook for the Kids ... without me having to log off of Windows.<br />
How do I do that? I do not want to just add the Kids Email accounts to my Outlook. <br />
I have a 3-4 year old version of Outlook but can upgrade/downfrade if necessary.<br />
These are all Home Emails ... No Exchange. All POP &amp;&nbsp;Imap email accounts.
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I have mutliple EMAIL Accounts in my Outlook right now, no problem
HOWEVER
What I want to do is use Outlook for the Kids ... without me having to log off of Windows.
How do I do that? I do not want to just add the Kids Email accounts to my Outlook. 
I have a 3-4 year old version of Outlook but can upgrade/downfrade if necessary.
These are all Home Emails ... No Exchange. All POP & Imap email accounts.

Multiple Outlook USERS on 1 Windows User Login?

Microsoft Outlook is a personal information manager from Microsoft, available as a part of the Microsoft Office suite. Although often used mainly as an email application, it also includes a calendar, task manager, contact manager, note-taker, journal, and web browser.