Samples or articles of 3rd party app XML Communication with XSD

I have to communicate with a 3rd party application via XML. The vendor furnishes an XSD and the VB.Net code that creates class and the XML Serialized Array List collections. But I have no idea how to use them. Can somebody point me to sample code or articles to get started?
John PittawayAsked:
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I'm not sure about your specific requirements but try to start from understanding XSD and generating XML from XSD:

Also, about serialization:
John PittawayAuthor Commented:
This looks like what I will need to complete my project. I may add to this reply in way of "lessons learned."
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