Sharepoint 2013 500 Internal Error

Server 2008R2
SQL 2012 Std
SharePoint 2013
After Installing SQL Reporting Services for SharePoint, I started receiving the above error whilst accessing the Home Page of our SharePoint Intranet site. I have attached the log file of the error.
fr000031.xml
Ronald HineNetwork & Fleet AdministratorAsked:
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martushaProduct managerCommented:
SharePoint 2013 requires SQL Server 2012 SP1 or later of the Reporting Services add-in and report server. Did you installed SP1 on your SQL?
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martushaProduct managerCommented:
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Ronald HineNetwork & Fleet AdministratorAuthor Commented:
Martusha,
I have SP2 for SQL 2012 installed. That was the first thing I did when I installed reporting services.

Update, I have now managed to get the site open with a new set of problems.
1. The home page displays "Sorry, this site hasn't been shared with you."
2. I can access the sub sites by navigating directly to them, I get the same message when I try and open documents.

Will have a look at that article you suggested.

In the event logs, I am getting a lot of these errors now.

The Execute method of job definition Microsoft.SharePoint.Publishing.Internal.PersistedNavigationTermSetSyncJobDefinition (ID f1b2fabc-7213-4072-b7b3-d64b089bbf97) threw an exception. More information is included below.

Requested registry access is not allowed.

Event ID:6398
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martushaProduct managerCommented:
TO know what job cause that problem go to CA and add that link to your url

http://yourCentralAdminURL:Port/_admin/JobEdit.aspx?JobId=f1b2fabc%2D7213%2D4072%2Db7b3%2Dd64b089bbf97

This is your given id (ID f1b2fabc-7213-4072-b7b3-d64b089bbf97) with replaced "-" to "%2D" to get job ID.
Let's see that job your get.
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Ronald HineNetwork & Fleet AdministratorAuthor Commented:
It goes to "Persisted Navigation Term Set Synchronization". I am getting a lot of profile Synchronization errors in the event log. These appear when I try to access the home page and get this error "Sorry, this site hasn't been shared with you"
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martushaProduct managerCommented:
Hmm. Firts of all I suggest to check if Reporting services was installed and configured correctly. Has the setup account the right permissions and so on.
You could follow this troubleshooting guide to check everything: https://msdn.microsoft.com/en-us/library/ms144289.aspx 
Maybe you will find some issues here.
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Ronald HineNetwork & Fleet AdministratorAuthor Commented:
Martusha,
Thanks for all your help, it seems that the errors and problems with the site keep shifting. However, the one constant error in the event log is;

 "The Execute method of job definition Microsoft.ReportingServices.SharePoint.SharedService.Service.DoWorkTimerJob (ID 08332802-e3a3-4102-9c60-96a75b9a22c0) threw an exception. More information is included below.

An unsecured or incorrectly secured fault was received from the other party. See the inner FaultException for the fault code and detail"

and

"An exception occurred when trying to issue security token: An unsecured or incorrectly secured fault was received from the other party. See the inner FaultException for the fault code and detail.."

And can get to some sites but when I try to open a document, it asks for credentials or "it cannot find the file".
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martushaProduct managerCommented:
I don't actually know if that solves the problem, but maybe it is because of a server time skew. The remote server and the client's system time must be within (typically) 10 minutes of each other. If they are not, security validation could fail.
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martushaProduct managerCommented:
And did you install sp1 updates on the Reporting Service-Sharepoint on wfe servers?
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Ronald HineNetwork & Fleet AdministratorAuthor Commented:
Martusha,
I have had a "SharePoint Expert" look at the server directly, and he is of the opinion, I agree, that SharePoint is beyond economical repair. They are going to extract the documents out of the database and then I will clean sharepoint of the server.

Thanks for all your help and I will close of this question.
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Ronald HineNetwork & Fleet AdministratorAuthor Commented:
The server is totally corrupt and I was only making it worst whilst applying suggested "fixes"
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