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just like you would use a cmd with net use \\server\share /user:johndoe password, you could use that information to start a process.<br />
Another method would be to use the windows dlls responsible for network mapping (WNetAddConnection in mpr.dll)
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How to make a network map drive using c#
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Using C# how to map a drive with userid and password

The .NET Framework is not specific to any one programming language; rather, it includes a library of functions that allows developers to rapidly build applications. Several supported languages include C#, VB.NET, C++ or ASP.NET.

.NET Programming

C# is an object-oriented programming language created in conjunction with Microsoft’s .NET framework. Compilation is usually done into the Microsoft Intermediate Language (MSIL), which is then JIT-compiled to native code (and cached) during execution in the Common Language Runtime (CLR).