Storage to be used for vSphere 5.x and 6

Difference b/w VVols and Datastores?

And mechanism difference with respect to SVMotion in vSphere 6?

any hardware change to be done before we go for upgrade form 5.x to 6
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Andrew Hancock (VMware vExpert / EE MVE^2)VMware and Virtualization ConsultantCommented:
Difference b/w VVols and Datastores?

http://blogs.vmware.com/vsphere/tag/vvols

And mechanism difference with respect to SVMotion in vSphere 6?

see here

What is new for vMotion in vSphere 6.0?

any hardware change to be done before we go for upgrade form 5.x to 6

Check the HCL, if your hardware is supported.

Check the VMware Hardware Compatability Lists HCL here

The VMware Hardware Compatibility List is the detailed lists showing actual vendor devices that are either physically tested or are similar to the devices tested by VMware or VMware partners. Items on the list are tested with VMware products and are known to operate correctly.Devices which are not on the list may function, but will not be supported by VMware.

http://www.vmware.com/go/hcl
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