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VMware, a software company founded in 1998, was one of the first commercially successful companies to offer x86 virtualization. The storage company EMC purchased VMware in 1994. Dell Technologies acquired EMC in 2016. VMware’s parent company is now Dell Technologies. VMware has many software products that run on desktops, Microsoft Windows, Linux, and macOS, which allows the virtualizing of the x86 architecture. Its enterprise software hypervisor for servers, VMware vSphere Hypervisor (ESXi), is a bare-metal hypervisor that runs directly on the server hardware and does not require an additional underlying operating system.
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I would not install vCenter Server on any server, which has anything currently running, including IIS. Is this a virtual server ? Do you have another server you could setup, or use the Linux Appliance (VCSA) and take the headache out of it, saved a WIndows OS license!
HOW TO: Install and Configure VMware vSphere vCenter Server 5.5 for Windows
HOW TO: Install and Configure VMware vSphere vCenter Server 6.0 for Windows
Have you considered using the Linux Appliance ? (VCSA), much easier now to install and get running.