OneDrive Access for Users Who Have Left

If we setup OneDrive for staff, what is the procedure for accessing their data if they leave the company. Obviously we could get their password from them, but I suspect there is another method.

If admins wanted access to their data even whilst they are here, what is the procedure for that? With an on-premise file server, the NTFS permissions normally allow them access or at the very least they can take control if they don't have explicit permissions assogned.
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Vasil Michev (MVP)Commented:
You can configure secondary administrators for ODFB by going to O365 Admin portal -> SharePoint -> User Profiles -> Setup my sites -> My site cleanup. Checking the "Enable access delegation" box will grant access to the person's manager and you can also specify (group of) administrators in the box below.

Or you can grant access explicitly by locating the user under User profiles -> Manage user profiles -> search -> right-click the result -> Manage site collection owners.

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KoenChange and Transition ManagerCommented:
Just a side comment here...

what do you mean ? 'Obviously we could get their password'... ? They'd be a fool giving you there password and in most countries (EU) you are not even allowed to ask it...

If the one drive is set up as their personal drive you have no right to access it even after they leave or you fire them... that would be an infringement of the privacy rules.
If it was set up as a company drive and this is clearly communicated than I guess you could access it.
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