Changing $PATH variable - OS X

I am trying to update my $Path variable.  However, I am getting the message the executable needs to be in the PATH.

I used this command to update the path

echo 'export PATH=/Users/rjw/Documents/Python' >>~/.bash_profile

But when you look at echo $PATH you get the following without my path above.

export PATH=${PATH}:~/android-sdk-mac/tools
export PS1="rjw "
export PATH="/usr/local/mysql/bin:$PATH"
alias ll='ls -lahG'
export PATH=/usr/local/mysql/bin:/usr/bin:/bin:/usr/sbin:/sbin:/usr/local/bin:/Users/rjw/android-sdk-mac/tools:/usr/local/mysql/bin

export PATH=/usr/local/mysql/bin:/usr/bin:/bin:/usr/sbin:/sbin:/usr/local/bin:/Users/rjw/android-sdk-mac/tools:/usr/local/mysql/bin:/usr/local/mysql/bin

export PATH=/usr/local/mysql/bin:/usr/bin:/bin:/usr/sbin:/sbin:/usr/local/bin:/Users/rjw/android-sdk-mac/tools:/usr/local/mysql/bin:/usr/local/mysql/bin

##
# Your previous /Users/rjw/.bash_profile file was backed up as /Users/rjw/.bash_profile.macports-saved_2016-01-13_at_10:05:16
##

# MacPorts Installer addition on 2016-01-13_at_10:05:16: adding an appropriate PATH variable for use with MacPorts.
export PATH="/opt/local/bin:/opt/local/sbin:$PATH"
# Finished adapting your PATH environment variable for use with MacPorts.


##
# Your previous /Users/rjw/.bash_profile file was backed up as /Users/rjw/.bash_profile.macports-saved_2016-07-26_at_16:54:01
##

# MacPorts Installer addition on 2016-07-26_at_16:54:01: adding an appropriate PATH variable for use with MacPorts.
export PATH="/opt/local/bin:/opt/local/sbin:$PATH"
# Finished adapting your PATH environment variable for use with MacPorts.


##
# Your previous /Users/rjw/.bash_profile file was backed up as /Users/rjw/.bash_profile.macports-saved_2016-07-26_at_17:07:46
##

# MacPorts Installer addition on 2016-07-26_at_17:07:46: adding an appropriate PATH variable for use with MacPorts.
export PATH="/opt/local/bin:/opt/local/sbin:$PATH"
# Finished adapting your PATH environment variable for use with MacPorts.


##
# Your previous /Users/rjw/.bash_profile file was backed up as /Users/rjw/.bash_profile.macports-saved_2016-07-26_at_17:13:45
##

# MacPorts Installer addition on 2016-07-26_at_17:13:45: adding an appropriate PATH variable for use with MacPorts.
export PATH="/opt/local/bin:/opt/local/sbin:$PATH"
# Finished adapting your PATH environment variable for use with MacPorts.
# Setting PATH for Python 3.5
# The original version is saved in .bash_profile.pysave
PATH="/Library/Frameworks/Python.framework/Versions/3.5/bin:${PATH}"
export PATH

I uninstalled macports if that is the problem and went to homebrew instead.