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Exchange is the server side of a collaborative application product that is part of the Microsoft Server infrastructure. Exchange's major features include email, calendaring, contacts and tasks, support for mobile and web-based access to information, and support for data storage.
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I am not sure what Exchange server you have and so here is the instruction for Exchange 2010: http://techgenix.com/managing-receive-connectors-part1/
Exchange 2013: https://practical365.com/exchange-server/exchange-2013-configure-smtp-relay-connector/