I can't access my synology from a host server on the local network, the host server is not joined the domain since it host the domain server (hyper-v). have no issue connecting from vmware machine (that are on my machine my machine is joined the domain) even thy are not joined the domain.
[Did have issue connecting even from joined domain workstatios, but I refreshed the DNS server and since that have no issue]
the hose is a server 2012
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