Php "Order By" not working correctly.

See my below code.

$query_rs_media_new_group = "SELECT supplier_code, title, url, description, description_item, brand, type, weight, category, section, width, label_artwork, min(id) as id 
							 FROM media_new 
							 WHERE media_binder = '1'
							 GROUP BY title 
							 ORDER BY brand";
$rs_media_new_group = mysql_query($query_rs_media_new_group, $conn_cmyuk) or die(mysql_error());
$row_rs_media_new_group = mysql_fetch_assoc($rs_media_new_group);
$totalRows_rs_media_new_group = mysql_num_rows($rs_media_new_group);

Select allOpen in new window

The order by brand is not coming out in the correct order. Could this be something to do with the alias or group by?