Outlook is bouncing my emails

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Yes all is correct. Here is a sample message:

Your message did not reach some or all of the intended recipients.

Subject: FW: GSE CC Meet Timing Bid
Sent: 7/20/2018 1:44 PM

The following recipient(s) cannot be reached:
...

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It is somewhat sporadic as to when it bounces but it has nothing to do with the recipient or what I am sending (ie: with or without attachments). I have three accounts in my outlook and it only happens to one of them but, again, that one will send just fine from webmail. I am puzzled.

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I thought of that myself...but I'm afraid I will lose my folders...even though they are in my web mail also. Is that not a concern?

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They are folders that I created myself but the are in my webmail as well. I will look into backing up the PST file and go from there. I will be in touch! Thanks for your help!!